Oxidation of alkanols

LC2.3.3.5
Oxidation of alkanols
Oxidation of alkanols

Description

In this experiment, the different reactions of primary, secondary and tertiary alkanols with potassium permanganate as oxidant are investigated. To do this, potassium permanganate is added to 1-butanol, 2-butanol and tert-butanol (2-methylpropan-2-ol). While primary and secondary butanol are oxidised, the tertiary 2-methylpropan-2-ol is not. Unlike 1-and 2-butanol, no colour change takes place here. The students realise that the structure of a substance has a great influence on possible reactions. They learn about the substance group of aldehydes and ketones.

Components of equipment sets

1 673 8420  4 
Sodium hydroxide solution, 1 mol/l, 500 ml LD
GHS05 Danger H314 H290
1 673 7800  4 
Sodium sulfite, 100 g LD
1 674 7920  4 
Sulfuric acid, diluted, approx. 2 N (= 10 %), 500 ml LD
GHS05 Warning H290 H315 H319
1 672 7000  4 
Potassium permanganate, 100 g LD
GHS03GHS07GHS09 Danger H272 H302 H410
1 675 3410  4 
Water, pure, 5 l LD
1 309 45  4 
Universal pencil LD
1 667 057  4 
Test tube rack metal, 20 mm Ø LD
4 665 9531  4 
Dropping pipette 150 mm x 7 mm Ø LD
4 665 9541  8 
Dropper bulb LD
3 664 0421  4 
Test tube Fiolax 16 mm x 160 mm LD
1 610 010  8 
Laboratory safety goggles LD
1 667 609  4 
Safety gloves, nitrile rubber, size 8 LD
1 671 1010  4 
1-Butanol, 1 l LD
GHS02GHS05GHS07 Danger H226 H302 H318 H315 H335 H336
1 671 1210  4 
2-Butanol, 1 l LD
GHS02GHS07 Warning H226 H319 H335 H336
1 671 1300  4 
Tertiary butanol, 100 ml LD
GHS02GHS07 Danger H225 H332 H319 H335
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